Safety msds data for hydrogen peroxide, 3% aqueous solution click here for data on dilute hydrogen peroxide in studentfriendly format, from the hsci project general synonyms. Violent reaction occurs upon contact with copper, copper alloys, lead alloys, and mineral acids. The information contained in this safety data sheet is believed to be. Wear appropriate protective gloves to prevent skin. Hazards identification classification this chemical is considered hazardous by the 2012 osha hazard communication standard 29 cfr. Completely submerge hydrogen peroxide contaminated clothing or other materials in water prior to drying. Material safety data sheet hydrogen peroxide solution. Cumene hydroperoxide c9h12o2 cid 6629 structure, chemical names, physical and. Sachtler gorlaeus laboratoria, rijksuniversiteit leiden, netherlands received may 19, 1972 cumene hydroperoxide dissolved in dodecane is rapidly decomposed by platinum and appreciably by silica gel or by. The oxidation of cumene and the decomposition of cumene.
Seek medical attention if irritation persists or if concerned. Central drug house p ltd 728 vardaan house new delhi2 india. Safety data sheet according to 29cfr19101200 and ghs rev. Msds material safety data sheet university of washington. Hydrogen peroxide, 2% ww safety data sheet according to federal register vol. Luperox cu80 polymer initiator is used for curing of highly reactive polyester or acrylic resins for lower exotherm and slower cure times. Cumene hydroperoxide is a colorless to light yellow liquid with a sharp, irritating odor. Wear chemical potective gloves made from pvc, nitrile or neoprene. Toxic and hazarous industrial chemicals safety manual. August 2004 section 1 chemical product and company identification msds name. May ignite combustibles wood paper, oil, clothing, etc. Identification of the substancemixture and of the companyundertaking. May react explosively upon contact with reducing reagents. Dihydrogen dioxide hydrogen dioxide hydroperoxide hydrogen peroxide.
The reaction is not selflimiting, as it is with the typical mechanical pulp situation. Classes of incompatible chemicals should be segregated from each other during storage, according to hazard class. Contain and collect spillage with noncombustible absorbent material such as clean sand, earth, diatomaceous earth or nonacidic clay and place into suitable properly labeled containers for prompt disposal. Uses advised against food, drug, pesticide or biocidal product use details of the supplier of the safety data sheet 2. Safety msds data for hydrogen peroxide, 3% aqueous solution. Cumene hydroperoxide is a peroxol that is cumene in which the alphahydrogen is replaced by a hydroperoxy group. En section 1 identification of the substance mixture and of the company undertaking product identifier product name gold cross hydrogen peroxide 3%. Contact with charcoal powder gives a strong exothermic reaction. It has a role as an oxidising agent, an environmental contaminant and a mycoplasma genitalium metabolite. Search results for cumene peroxide at sigmaaldrich. Although nonflammable, it is a powerful oxidizing agent that can cause spontaneous combustion.
A cumene hydrogen peroxide catalyst to be used with arc s7, s7 ar, nve, nve vc, t7 ar and t7 ar vc. Hydrogen peroxide is a colorless liquid at room temperature with a bitter taste. Indication of any immediate medical attention and special treatment needed if you feel unwell, seek medical advice show the label where possible. Cumene hydroperoxide is a colorless to pale yellow liquid chemical used as a polymerization inhibitor particularly in redox systems and to manufacture organic peroxides, primarily dicumylperoxide, which are used in the manufacture of plastic resins and as initiators in chemical reactions. Show this safety data sheet to the doctor in attendance. Hydrogen peroxide, 30% revision date 25nov2019 stot repeated exposure none known aspiration hazard no information available symptoms effects,both acute and delayed no information available endocrine disruptor informationno information available other adverse effects the toxicological properties have not been fully investigated. Hydrogen 0 4 0 hydrochloric acid 3 0 0 hydrobromic acid 3 0 0 hydrofluoric acid 4 0 0 hydrogen peroxide 35% to 52% by weight 2 0 1 ox hydrogen sulfide 3 4 0 hydroquinone 2 1 0 isoamyl acetate 1 3 0. To ensure product purity, interoxpico grade hydrogen peroxide is shipped.
Cumene hydroperoxide is an organic hydroperoxide intermediate in the cumene process for synthesizing phenol and acetone from benzene and propene. Cumene hydroperoxide is a peroxol that is cumene in which the alpha hydrogen is replaced by a hydroperoxy group. Wear appropriate protective eyeglasses or chemical safety goggles as described by oshas eye and face protection regulations in 29 cfr 1910. First aid measures eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Incompatibility of common laboratory chemicals when certain hazardous chemicals are stored or mixed together, violent reactions may occur because the chemicals are unsuitable for mixing, or are incompatible. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. Cumene 2 3 0 cupric nitrate 1 0 0 ox cyanogen 4 4 2 cyanogen bromide 3 0 2.
Hydrogen peroxide page 2 of 6 determining your exposure reproductive hazard read the product manufacturers material safety data sheet msds and the label to determine product ingredients and important safety and health information. Identification of the substancemixture and of the companyundertaking 1. Cumene hydroperoxide is an epoxidation reagent for allylic alcohols and fatty acid esters. Hydrogen peroxide is unstable, decomposing readily to oxygen and water with release of heat. Products of decomposition of cumene hydroperoxide are methylstyrene, acetophenone, and cumyl alcohol. Chesterton company 860 salem street groveland, ma 018341507, usa tel. Organic peroxides are organic compounds containing the peroxide functional group roor. Chemical splash goggles andor face shield must be worn when possibility exist for eye contact due to splashing or spraying liquid. Contact with combustibleorganic material may cause fire. Cumene hydroperoxide safety data sheet according to federal register vol. Its formula is c 6 h 5 cch 3 2 ooh one of the key uses for the material is as a free radical. Dicup dicumyl peroxide is available in pure form or as supported grades 40% peroxide on an inorganic substrate or as a rubber masterbatch.
Peroxide 6%,stabilized created by global safety management, 184355161. Gpx cumene hydroperoxide safety data sheet supersedes revision. Hydrogen peroxide, 30% ww safety data sheet according to federal register vol. Also measured are the ease of burning, sensitivity to rate of heat rise, thermal stability, self accelerating decompostion temperature and ignition or autoignition characteristics. Hydrogen peroxide solution material safety data sheet cas. Toxicological information the toxicological effects of this product have not been thoroughly studied. In this process, cumene hydroperoxide and sulfuric acid are reacted in a reflux cooled reactor the products of which are transported under inhibited conditions to a plug flow reactor, and are reacted to produce phenol, acetone, and alphamethylstyrene. Residual hydrogen peroxide, if allowed to dry on materials such as paper, fabrics, cotton, leather, wood or other combustibles, can cause the material to ignite and result in a fire.
Phenol material safety data sheet cas no 108952 sdsmsds. Hydrogen peroxide, aqueous solution, with not less than 8% but less than 20% hydrogen peroxide. Joubnal of catalysis 29, 367373 1973 the oxidation of cumene and the decomposition of cumene hydroperoxide on silver, copper, and platinum j. Wear appropriate protective eyeglasses or chemical safety goggles as described by oshas eye and face. Identification of the substancepreparation and of the companyundertaking product name phenol unid no un1671 synonyms phenol molecular weight 94. Mixtures name product identifier % ghs us classification water casno.
Availability interoxpico hydrogen peroxide is available in bulk quantities at 31% concentration from solvay chemicals deer park, texas, and bernburg, germany plants. Since cumene hydroperoxide, as a tertiary alkyl hydroperoxide, is much more stable than ethylbenzene hydroperoxide, the oxidation can be taken to a higher conversion with still reasonable selectivity. Thus, organic peroxides are useful as initiators for some types of. It also acts as an initiator for radical polymerization.
Dicumyl peroxide is a white powder with a characteristic odor. Gpx cumene hydroperoxide safety data sheet section 2. A process for the decomposition of cumene hydroperoxide to phenol, acetone, and alphamethylstyrene is presented. O bond easily breaks, producing free radicals of the form ro the dot represents an unpaired electron. Details of the supplier of the safety data sheet company. Cumene hydroperoxide is obtained by oxidizing cumene with air, usually in a cascade of stirredtank reactors or bubble columns at temperatures in the range of 100140 c and a pressure of 67 bar and usually with small amounts of a buffer to prevent acids from building up. Sigmaaldrich offers a number of cumene hydroperoxide products. Cumene hydroperoxide material safety data sheet cas. Cumene hydroperoxide material safety data sheet cas no 80. May cause damage to organs through prolonged or repeated exposure. Us state regulations the product andor components does not appear on any state right to know lists or the canadian ingredient disclosure list idl at. Hydrogen peroxide, aqueous solution, with not less than 20% but not more than 60% hydrogen peroxide stabilized as.
H341 h373 h411 precautionary statements p260 p280 suspected of causing genetic defects. Cumene hydroperoxide material safety data sheet cas no 8015. Msds hydrogen peroxide, 2040% ww aqueous solutions for ricca, spectropure, red bird, and solutions plus brands teratology birth defect information. Ingredient source value 0007722841 hydrogen peroxide osha twa 1 ppm 1. Small amounts of gaseous hydrogen peroxide occur naturally in the air. Carbamide peroxide recommended use laboratory chemicals. Hydrogen peroxide of various concentrations is unstable in presence of catalytic contaminations, heat sources and uv light. Cumene hydroperoxide technical grade, 80% sigmaaldrich. Mutation data cited in registry of toxic effects of chemical substances for hydrogen peroxide. Product and company identification product identifier product name hydrogen peroxide 31% rgs2 casno 7722841 recommended use.
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